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this is what Pyro head replacements should be and not anything that is random or cute.
https://wiki.teamfortress.com/wiki/Foster%27s_Facade
https://wiki.teamfortress.com/wiki/Last_Breath
https://wiki.teamfortress.com/wiki/HazMat_Headcase
https://wiki.teamfortress.com/wiki/Triclops
https://wiki.teamfortress.com/wiki/Winter_Wonderland_Wrap
https://wiki.teamfortress.com/wiki/Mair_Mask
https://wiki.teamfortress.com/wiki/Air_Raider
https://wiki.teamfortress.com/wiki/Beast_from_Below
https://wiki.teamfortress.com/wiki/Rugged_Respirator
https://wiki.teamfortress.com/wiki/Blizzard_Breather
https://wiki.teamfortress.com/wiki/Mishap_Mercenary
https://wiki.teamfortress.com/wiki/Phobos_Filter
https://wiki.teamfortress.com/wiki/Arthropod%27s_Aspect
https://wiki.teamfortress.com/wiki/Firefly
https://wiki.teamfortress.com/wiki/Airtight_Arsonist
https://wiki.teamfortress.com/wiki/Masked_Loyalty
TF2 Workshop isn't a mod workshop. you can only use them in-game once they get accepted.
But some creators makes seperate download links on websites such as Mods.TF or Gamebanana.