Yes. The presets are defined in xml

https://github.com/Mehni/kNumbers/blob/58cc89ff841e6eac35685791e457fcd1e21bb062/Defs/PawnTableDef/Numbers_PawnTableDef.xml#L188

You can change that manually. The names in the <li> refers to a PawnColumnDef. You can use the ones defined by vanilla, such as Label, the ones added by Numbers, such as Numbers_Equipment or even the ones generated by code. Their format follows Numbers_ModName_TypeOfDef_Defname. so that's Numbers_RimWorld_NeedDef_Mood for the NeedDef mood in RimWorld.

Note that your changes will be overwritten next time I update the mod. If you want to avoid that, you could create a patch mod. Or local copy.

Thank you very much! I would love to make a patch, but I have no idea how. Perhaps YouTube can show me. There are a couple I'd like to change the order or add a column, but I can't be bothered to click twice.

I was poking around in the files and literally laughed out loud when I saw a file that was named something along the lines of I cannot believe I have to make this ffs.